Endo M, Muramatsu H, Hayashi T, Kim Y A, Terrones M, Dresselhaus M S
Faculty of Engineering, Shinshu University, 4-17-1 Wakasato, Nagano-shi 380-8553, Japan.
Nature. 2005 Feb 3;433(7025):476. doi: 10.1038/433476a.
Double-walled carbon nanotubes are needed in a pure, highly crystalline form before features such as their electronic properties, thermal transport and mechanical behaviour can be investigated. Here we fabricate a paper-like material that consists of hexagonally packed bundles of clean, coaxial carbon nanotubes whose double walls vary little in diameter; it is prepared in high yields using chemical-vapour deposition with a conditioning catalyst and two-step purification. Our results will enable investigation of the physical properties of double-walled carbon nanotubes, which are predicted to be superior to those of both their single- and multiwalled relatives.
在研究双壁碳纳米管的电子特性、热传导和机械性能等特征之前,需要获得纯净的、高度结晶形式的双壁碳纳米管。在此,我们制备了一种纸状材料,它由清洁的、同轴的碳纳米管六边形排列的管束组成,这些碳纳米管的双壁直径变化很小;通过使用经过预处理的催化剂进行化学气相沉积和两步纯化,可高产率地制备这种材料。我们的研究结果将有助于对双壁碳纳米管的物理性质进行研究,预计其物理性质优于单壁和多壁碳纳米管。