Legrouri K, Khouya E, Ezzine M, Hannache H, Denoyel R, Pallier R, Naslain R
Laboratoire des Matériaux ThermoStructuraux, Département de chimie, Faculté des Sciences Ben M'sik, Université Hassan II-Mohammedia, BP 7955 Casablanca, Maroc.
J Hazard Mater. 2005 Feb 14;118(1-3):259-63. doi: 10.1016/j.jhazmat.2004.11.004.
Activated carbon has been prepared from molasses, a natural precursor of vegetable origin resulting from the sugar industry in Morocco. The preparation of the activated carbon from the molasses has been carried out by impregnation of the precursor with sulphuric acid, followed by carbonisation at varying conditions (temperature and gas coverage) in order to optimize preparation parameters. The influence of activation conditions was investigated by determination of adsorption capacity of methylene blue and iodine, the BET surface area, and the pore volume of the activated carbon were determined while the micropore volume was determined by the Dubinin-Radushkevich (DR) equation. The activated materials are mainly microporous and reveal the type I isotherm of the Brunauer classification for nitrogen adsorption. The activated carbons properties in this study were found for activation of the mixture (molasses/sulphuric acid) in steam at 750 degrees C. The samples obtained in this condition were highly microporous, with high surface area (> or =1200 m2/g) and the maximum adsorption capacity of methylene blue and iodine were 435 and 1430 mg/g, respectively.
活性炭由糖蜜制备而成,糖蜜是摩洛哥制糖业产生的一种天然植物源前驱体。以糖蜜为原料制备活性炭的过程是先将前驱体用硫酸浸渍,然后在不同条件(温度和气体覆盖率)下进行碳化,以优化制备参数。通过测定亚甲基蓝和碘的吸附容量来研究活化条件的影响,测定了活性炭的BET表面积和孔体积,同时用杜比宁-拉杜什克维奇(DR)方程测定了微孔体积。活化材料主要为微孔结构,呈现出布鲁诺尔分类中用于氮气吸附的I型等温线。本研究发现,在750℃蒸汽中对混合物(糖蜜/硫酸)进行活化可得到活性炭的这些性质。在此条件下获得的样品具有高度微孔结构,表面积高(≥1200 m²/g),亚甲基蓝和碘的最大吸附容量分别为435和1430 mg/g。