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利用抗生素废料制备的活性炭去除水溶液中的汞(II)。

Use of an activated carbon from antibiotic waste for the removal of Hg(II) from aqueous solution.

作者信息

Budinova Temenuzhka, Petrov Nartzislav, Parra Jose, Baloutzov Venelin

机构信息

Institute of Organic Chemistry, Bulgarian Academy of Sciences, Acad. G.Bonchev 9, str. Sofia 1113, Bulgaria.

出版信息

J Environ Manage. 2008 Jul;88(1):165-72. doi: 10.1016/j.jenvman.2007.02.005. Epub 2007 Apr 10.

Abstract

Porous carbon has been prepared from waste antibiotic material by a chemical activation method using K(2)CO(3) as an activating reagent. Carbon was studied systematically by the adsorption of nitrogen and iodine. It was found that the process parameters such as activation temperature and activation time are crucial for preparing high-quality activated carbon. The proper choice of the preparation conditions allows to produce microporous activated carbon with a micropore volume up to 0.492 cm(3)/g and a BET surface area of 1260 m(2)/g. Adsorption of mercury(II) from an aqueous solution on antibiotic carbon was investigated under the varying conditions of agitation time, metal ion concentration and pH. The adsorption capacity of the carbon is 129 mg/g.

摘要

采用碳酸钾作为活化剂,通过化学活化法由废弃抗生素材料制备了多孔碳。通过氮气和碘吸附对碳进行了系统研究。发现诸如活化温度和活化时间等工艺参数对于制备高质量活性炭至关重要。制备条件的恰当选择能够制得微孔体积高达0.492 cm³/g且BET表面积为1260 m²/g的微孔活性炭。在搅拌时间、金属离子浓度和pH值变化的条件下,研究了抗生素碳对水溶液中汞(II)的吸附。该碳的吸附容量为129 mg/g。

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