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双金属镧系配合物的pH依赖性自组装

pH dependent self-assembly of dimetallic lanthanide complexes.

作者信息

Faulkner Stephen, Burton-Pye Benjamin P

机构信息

Department of Chemistry, University of Manchester, Oxford Road, Manchester, UK M13 9PL.

出版信息

Chem Commun (Camb). 2005 Jan 14(2):259-61. doi: 10.1039/b412329h. Epub 2004 Nov 19.

DOI:10.1039/b412329h
PMID:15724205
Abstract

pH dependent self-association has been observed in a series of DO3A-derived lanthanide complexes bearing a carboxylate group that can act as a bridging ligand at high pH, switching on the luminescence from the lanthanide.

摘要

在一系列带有羧基的DO3A衍生镧系配合物中观察到了pH依赖性自缔合现象,该羧基在高pH值时可作为桥连配体,开启镧系元素的发光。

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