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模拟夹带剂对溶质在超临界二氧化碳中溶解度的影响。

Modeling the entrainer effects on solubility of solutes in supercritical carbon dioxide.

作者信息

Jouyban Abolghasem, Khoubnasabjafari Maryam, Chan Hak-Kim

机构信息

School of Pharmacy and Drug Applied Research Center, Tabriz University of Medical Sciences, Iran.

出版信息

Chem Pharm Bull (Tokyo). 2005 Mar;53(3):290-5. doi: 10.1248/cpb.53.290.

Abstract

Applicability of a previously published equation for calculating the solubility of solutes in supercritical carbon dioxide was extended to calculate the solubility in entrained supercritical carbon dioxide employing 42 experimental data sets collected from the literature. The accuracy of the proposed model was evaluated by calculating both the average absolute relative deviation and the individual absolute relative deviation. The proposed model showed superiority to a previously published similar model, from both correlation and prediction points of view.

摘要

先前发表的用于计算溶质在超临界二氧化碳中溶解度的方程的适用性得到了扩展,以利用从文献中收集的42个实验数据集来计算溶质在夹带超临界二氧化碳中的溶解度。通过计算平均绝对相对偏差和个体绝对相对偏差来评估所提出模型的准确性。从相关性和预测性的角度来看,所提出的模型均优于先前发表的类似模型。

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