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亚甲基蓝在黄麻纤维活性炭上的吸附:动力学与平衡研究

Adsorption of methylene blue onto jute fiber carbon: kinetics and equilibrium studies.

作者信息

Senthilkumaar S, Varadarajan P R, Porkodi K, Subbhuraam C V

机构信息

Department of Chemistry, Faculty of Engineering, PSG College of Technology, Coimbatore 641 004, India.

出版信息

J Colloid Interface Sci. 2005 Apr 1;284(1):78-82. doi: 10.1016/j.jcis.2004.09.027.

Abstract

Jute fiber obtained from the stem of a plant was used to prepare activated carbon using phosphoric acid. Feasibility of employing this jute fiber activated carbon (JFC) for the removal of Methylene blue (MB) from aqueous solution was investigated. The adsorption of MB on JFC has found to dependent on contact time, MB concentration and pH. Experimental result follows Langmuir isotherm model and the capacity was found to be 225.64 mg/g. The optimum pH for the MB removal was found to be 5-10. The kinetic data obtained at different concentrations have been analyzed using a pseudo-first-order, pseudo-second-order equation, intraparticle diffusion and Elovich equation. Among the kinetic models studied, the intraparticle diffusion was the best applicable model to describe the adsorption of MB onto JFC.

摘要

从植物茎部获取的黄麻纤维被用于使用磷酸制备活性炭。研究了采用这种黄麻纤维活性炭(JFC)从水溶液中去除亚甲基蓝(MB)的可行性。发现MB在JFC上的吸附取决于接触时间、MB浓度和pH值。实验结果符合朗缪尔等温线模型,吸附容量为225.64 mg/g。发现去除MB的最佳pH值为5至10。使用准一级、准二级方程、颗粒内扩散和埃洛维奇方程分析了在不同浓度下获得的动力学数据。在所研究的动力学模型中,颗粒内扩散是描述MB在JFC上吸附的最佳适用模型。

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