Li Meng, Zhang Pingxiu, Wang Qianfang, Yu Ningya, Zhang Xiaomin, Su Shengpei
National and Local Joint Engineering Lab for New Petro-Chemical Materials and Fine Utilization of Resources, Hunan Normal University, Changsha 410081, China.
Polymers (Basel). 2023 Apr 28;15(9):2110. doi: 10.3390/polym15092110.
Understanding how to develop highly efficient and robust adsorbents for the removal of organic dyes in wastewater is crucial in the face of the rapid development of industrialization. Herein, d-TiCT nanosheets (MXene) were combined with sodium alginate (SA), followed by electrospinning and successive Ca-mediated crosslinking, giving rise to a series of SA/MXene nanofiber membranes (NMs). The effects of the MXene content of the NMs on the adsorption performance for methylene blue (MB) were investigated systemically. Under the optimum MXene content of 0.74 wt.%, SA/MXene NMs possessed an MB adsorption capacity of 440 mg/g, which is much higher than SA/MXene beads with the same MXene content, pristine MXene, or electrospinning SA NMs. Furthermore, the optimum SA/MXene NMs showed excellent reusability. After the adsorbent was reused ten times, both the MB adsorption capacity and removal rate could remain at 95% of the levels found in the fresh samples, which indicates that the electrospinning technique has great potential for developing biomass-based adsorbents with high efficiency.
面对工业化的快速发展,了解如何开发高效且耐用的吸附剂以去除废水中的有机染料至关重要。在此,将d-TiCT纳米片(MXene)与海藻酸钠(SA)结合,随后进行静电纺丝和连续的钙介导交联,从而得到一系列SA/MXene纳米纤维膜(NMs)。系统研究了NMs中MXene含量对亚甲基蓝(MB)吸附性能的影响。在最佳MXene含量为0.74 wt.%时,SA/MXene NMs对MB的吸附容量为440 mg/g,远高于具有相同MXene含量的SA/MXene珠、原始MXene或静电纺丝SA NMs。此外,最佳的SA/MXene NMs表现出优异的可重复使用性。吸附剂重复使用十次后,MB的吸附容量和去除率均可保持在新鲜样品的95%,这表明静电纺丝技术在开发高效生物质基吸附剂方面具有巨大潜力。