Kim Woo Han, Jung Jae Hoon, Sung Lee Taek, Lim Sang Min, Lee Eun
Department of Chemistry, College of Natural Sciences, Seoul National University, Seoul 151-747, Korea.
Org Lett. 2005 Mar 17;7(6):1085-7. doi: 10.1021/ol0500160.
[reaction: see text] Possible structures of feigrisolide C were synthesized via ring-closing olefin metathesis reaction of a diester derivative prepared from 8-epi-nonactic acid, but physical characteristics of the synthetic samples did not match with those of the natural sample of feigrisolide C.
[反应:见正文] 通过由8-表壬酸制备的二酯衍生物的闭环烯烃复分解反应合成了费格立内酯C的可能结构,但合成样品的物理特性与费格立内酯C天然样品的物理特性不匹配。