η3-[(η5-Cp*)(CO)2Fe-AsPC(SiMe3)2]M(CO)2(η5-Cp)（M = Mo，W）的合成与分子结构：首个具有η3-砷磷烯丙基配体的配合物
Syntheses and molecular structures of eta3-[(eta5-Cp*)(CO)2Fe-AsPC(SiMe3)2]M(CO)2(eta5-Cp)(M = Mo, W): the first complexes featuring eta3-arsaphosphaallyl ligands.
作者信息
Weber Lothar, Bayer Philipp, Stammler Hans-Georg, Neumann Beate
机构信息
Fakultät für Chemie der Universität Bielefeld, Universitätsstr. 25, D-33615, Bielefeld, Germany.
出版信息
Chem Commun (Camb). 2005 Mar 28(12):1595-7. doi: 10.1039/b414621b. Epub 2005 Jan 27.
DOI:10.1039/b414621b
PMID:15770271
Abstract
Reaction of (eta5-Cp)(CO)2M=P=C(SiMe3)2 4a (M = Mo) and 4b (M = W) with (eta5-Cp*)(CO)2Fe-As=C(NMe2)2 5 affords the eta3-1-arsa-2-phosphaallyl complexes [(eta5-Cp*)(CO)2Fe-AsPC(SiMe3)2]M(CO)2(eta5-Cp) 6a and 6b, the molecular structures of which were determined by X-ray analyses.
摘要
（η⁵-Cp）（CO）₂M=P=C（SiMe₃）₂ 4a（M = Mo）和4b（M = W）与（η⁵-Cp*）（CO）₂Fe-As=C（NMe₂）₂ 5反应，生成η³-1-砷-2-磷烯丙基配合物[（η⁵-Cp*）（CO）₂Fe-AsPC（SiMe₃）₂]M（CO）₂（η⁵-Cp）6a和6b，其分子结构通过X射线分析确定。
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