一种基于戊烯基双负离子的烯-1,5-二醇汇聚合成策略。
A pentenyl dianion-based strategy for convergent synthesis of ene-1,5-diols.
作者信息
Bahadoor Adilah B, Flyer Alec, Micalizio Glenn C
机构信息
Sterling Chemistry Laboratory, Department of Chemistry, Yale University, New Haven, Connecticut 06520-8107, USA.
出版信息
J Am Chem Soc. 2005 Mar 23;127(11):3694-5. doi: 10.1021/ja050039+.
PMID:15771493
Abstract
A convergent two-step process is described for the synthesis of ene-1,5-diols that provides for union of two carbonyl electrophiles via a formal pentenyl dianion equivalent.
摘要
描述了一种用于合成烯-1,5-二醇的收敛两步法，该方法通过一个形式上的戊烯基双负离子等价物实现两个羰基亲电试剂的结合。
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