一种席夫碱扩展卟啉大环化合物，它作为一种通用的双核配体用于第一周期晚期过渡金属。
A Schiff base expanded porphyrin macrocycle that acts as a versatile binucleating ligand for late first-row transition metals.
作者信息
Sessler Jonathan L, Tomat Elisa, Mody Tarak D, Lynch Vincent M, Veauthier Jacqueline M, Mirsaidov Utkir, Markert John T
机构信息
Department of Chemistry and Biochemistry, The University of Texas at Austin, 1 University Station A5300, Austin, Texas 78712-0165, USA.
出版信息
Inorg Chem. 2005 Apr 4;44(7):2125-7. doi: 10.1021/ic048412m.
The coordination chemistry of the Schiff base polypyrrolic octaaza macrocycle 1 toward late first-row transition metals was investigated. Binuclear complexes with the divalent cations Ni(II), Cu(II), and Zn(II) and with the monovalent cation Cu(I) were prepared and characterized. Air oxidation of the Cu(I) ions in the latter complex to their divalent oxidation state resulted in a change in the coordination mode relative to the macrocycle.
研究了席夫碱多吡咯八氮大环1与第一周期晚期过渡金属的配位化学。制备并表征了与二价阳离子镍（II）、铜（II）和锌（II）以及一价阳离子铜（I）形成的双核配合物。后一种配合物中铜（I）离子被空气氧化为其二价氧化态，导致相对于大环的配位模式发生变化。
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