席夫碱扩环卟啉的双核有机金属钌配合物

Binuclear organometallic ruthenium complexes of a Schiff base expanded porphyrin.

作者信息

Cuesta Luciano, Tomat Elisa, Lynch Vincent M, Sessler Jonathan L

机构信息

Department of Chemistry and Biochemistry, University of Texas, 1 University Station A5300, Austin, TX 78712-0165, USA.

出版信息

Chem Commun (Camb). 2008 Aug 28(32):3744-6. doi: 10.1039/b807126h. Epub 2008 Jul 1.

DOI:10.1039/b807126h

PMID:18685763

Abstract

The synthesis of binuclear organometallic ruthenium complexes of an expanded porphyrin-type macrocycle is reported; pyrrolic hydrogen bonding donors were found to interact with ancillary ligands in the primary coordination sphere and to stabilize coordinated dioxygen in an eta(2)-fashion.

摘要

报道了一种扩展卟啉型大环双核有机金属钌配合物的合成；发现吡咯氢键供体与一级配位球中的辅助配体相互作用，并以η(2)方式稳定配位的双氧。