一种配位氧硼烷的合成与表征：硼氧双键的路易斯酸稳定作用
Synthesis and characterization of a coordinated oxoborane: Lewis acid stabilization of a boron-oxygen double bond.
作者信息
Vidovic Dragoslav, Moore Jennifer A, Jones Jamie N, Cowley Alan H
机构信息
Department of Chemistry and Biochemistry, The University of Texas at Austin, 1 University Station A5300, Austin, TX 78712-0165, USA.
出版信息
J Am Chem Soc. 2005 Apr 6;127(13):4566-7. doi: 10.1021/ja0507564.
PMID:15796509
Abstract
The first example of a stable oxoborane monomer (LB=O) stabilized by complexation to AlCl3 has been prepared by the reaction of LAlCl2 with BCl3 followed by treatment with H2O in CH2Cl2 (L = [HC(CMe)2(NC6F5)2]). DFT calculations reveal that considerable boron-oxygen double bond character is retained in this complex.
摘要
通过使LAlCl₂与BCl₃反应，然后在二氯甲烷中用H₂O处理，制备出了首例通过与AlCl₃络合而稳定的稳定氧硼烷单体（LB=O）（L = [HC(CMe)₂(NC₆F₅)₂]）。密度泛函理论计算表明，该络合物中保留了相当程度的硼氧双键特征。
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