Loh Ying Kai, Chong Che Chang, Ganguly Rakesh, Li Yongxin, Vidovic Dragoslav, Kinjo Rei
Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Nanyang Link 21, Singapore 637371, Singapore.
Chem Commun (Camb). 2014 Aug 11;50(62):8561-4. doi: 10.1039/c4cc03379e.
The first example of 1,2,4,3-triazaborole-based oxoborane has been synthesized via hydrogen migration upon the coordination of AlCl3 to the corresponding borinic acid. X-ray diffraction analysis and computational study disclosed the partial B[double bond, length as m-dash]O double-bond property.
通过氯化铝与相应硼酸配位时的氢迁移，合成了首个基于1,2,4,3-三氮杂硼戊环的氧硼烷。X射线衍射分析和计算研究揭示了部分B=O双键性质。
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