Borissov D, Ziegler A, Höger S, Freyland W
University of Karlsruhe, Institute of Physical Chemistry, Kaiserstrasse 12, 76128 Karlsruhe, Germany.
Langmuir. 2004 Mar 30;20(7):2781-4. doi: 10.1021/la030424h.
Self-assembled monolayers of shape-persistent macrocycles have been adsorbed on highly oriented pyrolytic graphite and Au(111) substrates. Their structure and binding characteristics have been investigated by scanning tunneling microscopy, X-ray photoelectron spectroscopy, and ultraviolet photoelectron spectroscopy experiments. Special functionalization of the macrocycles for the first time has enabled their self-assembling and binding on a metal substrate and opened a new route for new functional nanostructures.