Zilman A, Safran S A, Sottmann T, Strey R
Department of Materials and Interfaces, Weizmann Institute, Rehovot, Israel 76100.
Langmuir. 2004 Mar 16;20(6):2199-207. doi: 10.1021/la0359732.
We predict theoretically the thermodynamics and relaxation kinetics of solutions of cylindrical branched micelles. Using a recently developed theory in combination with the experimental data, we explain the unusual, inverted temperature dependence of the phase separation observed in wormlike micelles and dilute microemulsions. We extend the model to treat the temperature dependence of the relaxation kinetics and explain the observations.
我们从理论上预测了圆柱形支化胶束溶液的热力学和弛豫动力学。结合最近发展的理论和实验数据，我们解释了在蠕虫状胶束和稀微乳液中观察到的相分离异常的、与温度呈反比的依赖性。我们扩展了该模型以处理弛豫动力学的温度依赖性并解释了这些观察结果。
