在温和条件下，由聚脲封装的醋酸钯（II）和四正丁基铵盐催化的高效间歇式和连续流动铃木交叉偶联反应。
Efficient batch and continuous flow Suzuki cross-coupling reactions under mild conditions, catalysed by polyurea-encapsulated palladium (II) acetate and tetra-n-butylammonium salts.
作者信息
Lee Connie K Y, Holmes Andrew B, Ley Steven V, McConvey Ian F, Al-Duri Bushra, Leeke Gary A, Santos Regina C D, Seville Jonathan P K
机构信息
Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, UK.
出版信息
Chem Commun (Camb). 2005 Apr 28(16):2175-7. doi: 10.1039/b418669a. Epub 2005 Mar 9.
Suzuki cross-coupling reactions are effected in both conventional organic solvents, under continuous flow conditions at 70 degree C, and in batch mode in supercritical carbon dioxide (scCO2), at temperatures as low as 40 degrees C in the presence of palladium(II) acetate microencapsulated in polyurea [PdEnCat] and tetra-n-butylammonium salts.
铃木交叉偶联反应既可以在传统有机溶剂中，于70摄氏度的连续流动条件下进行，也可以在超临界二氧化碳（scCO2）中，在聚脲微囊化的醋酸钯（II）[PdEnCat]和四正丁基铵盐存在下，在低至40摄氏度的温度下以间歇模式进行。
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