Schubert H, Agatha G
Derm Beruf Umwelt. 1979;27(2):49-52.
Until now allergic contact dermatitis to polychloroprene glues was thought to be caused by uncondensed p-tert.-butylphenol (monomer) or by the p-tert. burylphenol formaldehyde resin molecule (polycondensate) as allergens. This opinion could not be verified. We found the following two contact allergens: 2-hydroxy-5-tert.-butylbenzyl alcohol and a four nuclear-condensate from four p-tert-butylphenol molecules linear combined by methylene bridges.
到目前为止,人们认为对氯丁橡胶胶水的过敏性接触性皮炎是由未缩合的对叔丁基苯酚(单体)或对叔丁基苯酚甲醛树脂分子(缩聚物)作为过敏原引起的。但这一观点无法得到证实。我们发现了以下两种接触性过敏原:2-羟基-5-叔丁基苄醇以及一种由四个对叔丁基苯酚分子通过亚甲基桥线性结合而成的四核缩合物。