Liu Ying, Lan Xiu-feng, Shen Zhong-hua, Lu Jian, Ni Xiao-wu
School of Science, Nanjing University of Science & Technology, Nanjing 210094, China.
Guang Pu Xue Yu Guang Pu Fen Xi. 2005 Feb;25(2):242-5.
Ethanol solution can emit visible fluorescence when induced by UV light. With emission spectral profiles similar on the whole, the peaks are red-shifted distinctly when the excitation light alters from 200 to 250 nm. And the spectral profiles of ethanol solutions with different concentrations are also red-shifted when induced by the same wavelength of excitation light. A thorough analysis of the rule of spectrum peaks that are red-shifted is carried out and discussed in theory and in experiment. Investigation on the intrinsic fluorescence spectrum of ethanol solution and its characteristics will contribute to the study of the fluorescence spectra when ethanol serves as a solute and hydrolysis catalyst. Especially, this study will also help to offer a sensitive method of the determination of ethanol.
乙醇溶液在紫外光诱导下能发出可见荧光。其发射光谱轮廓总体相似,但当激发光从200nm变为250nm时,峰值明显红移。并且,在相同波长激发光诱导下,不同浓度乙醇溶液的光谱轮廓也会发生红移。本文对光谱峰值红移规律进行了深入分析,并从理论和实验两方面进行了探讨。对乙醇溶液的本征荧光光谱及其特性进行研究,将有助于研究乙醇作为溶质和水解催化剂时的荧光光谱。特别是,本研究还将有助于提供一种灵敏的乙醇测定方法。