Fialkowski M, Campbell C J, Bensemann I T, Grzybowski B A
Department of Chemical and Biological Engineering, Northwestern University, Evanston, Illinois 60208, USA.
Langmuir. 2004 Apr 27;20(9):3513-6. doi: 10.1021/la036298z.
This paper discusses absorption of water by thin, dry films of gelatin. Experiments using a wet-stamping technique were performed to characterize water uptake in terms of (i) equilibrium profiles of the water density inside the gel and (ii) the kinetics of water absorption. It was found that, in contrast to pure gelatin films, which absorb water approximately uniformly, films of gelatin doped with ionic additives have exponentially decaying equilibrium water profiles. The process of water absorption by both doped and undoped gels was described by a theoretical model based on the minimization of grand potential functional. The results of this model are in agreement with the experiment.
本文讨论了干燥明胶薄膜对水的吸收情况。采用湿压印技术进行实验,以从以下两个方面表征水的吸收:(i)凝胶内部水密度的平衡分布;(ii)水吸收的动力学。研究发现,与大致均匀吸水的纯明胶薄膜不同,掺杂离子添加剂的明胶薄膜具有指数衰减的平衡水分布。基于巨势泛函最小化的理论模型描述了掺杂和未掺杂凝胶的吸水过程。该模型的结果与实验结果一致。