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Ruthenium-catalyzed decarboxylative insertion of electrophiles.

作者信息

Wang Chao, Tunge Jon A

机构信息

Department of Chemistry, University of Kansas, Lawrence, Kansas 66045, USA.

出版信息

Org Lett. 2005 May 26;7(11):2137-9. doi: 10.1021/ol050466s.

DOI:10.1021/ol050466s
PMID:15901153
Abstract

[reaction: see text]. A ruthenium complex, Cp*Ru(bipyridyl)Cl, has been developed as a catalyst for the first regioselective tandem Michael addition-allylic alkylation of activated Michael acceptors. The net transformation is the decarboxylative insertion of Michael acceptors into allyl beta-ketoesters.

摘要

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