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壳聚糖水凝胶珠对水溶液中模型阴离子染料曙红Y的吸附

Adsorption of a model anionic dye, eosin Y, from aqueous solution by chitosan hydrobeads.

作者信息

Chatterjee Sudipta, Chatterjee Sandipan, Chatterjee Bishnu P, Das Akhil R, Guha Arun K

机构信息

Department of Biological Chemistry, Indian Association for the Cultivation of Science, Jadavpur, Kolkata 700032, India.

出版信息

J Colloid Interface Sci. 2005 Aug 1;288(1):30-5. doi: 10.1016/j.jcis.2005.02.055.

Abstract

The process of sorption is being increasingly used for ecofriendly and economic remediation of textile dye effluents. The present model study deals with the adsorption of a model anionic dye, eosin Y, from wastewater using conditioned chitosan hydrobeads. Conditioning reduced the pH sensitivity and maintained the maximum sorption capacity of the beads near pH 8. To understand the chemicophysical characteristics of the adsorption process we studied, the kinetics and isotherm behavior of the system. It was observed that temperature played a significant role in the process. The Langmuir model was found to be most appropriate for the description of the adsorption process. The kinetic results followed a second-order equation. It was observed that 1 g of chitosan adsorbed approximately 76 mg of eosin Y. The dye was desorbed from the beads by changing the pH of the solution, and the conditioned chitosan beads were reused five times without any loss of mechanical and chemical efficacy.

摘要

吸附过程越来越多地用于纺织染料废水的环保且经济的修复。本模型研究涉及使用经处理的壳聚糖水凝胶珠从废水中吸附模型阴离子染料曙红Y。处理降低了pH敏感性,并使珠子在pH 8附近保持最大吸附容量。为了解我们所研究的吸附过程的化学物理特性,我们研究了该系统的动力学和等温线行为。观察到温度在该过程中起重要作用。发现朗缪尔模型最适合描述吸附过程。动力学结果遵循二级方程。观察到1 g壳聚糖吸附了约76 mg曙红Y。通过改变溶液的pH值使染料从珠子上解吸,并且经处理的壳聚糖珠重复使用了五次,而没有任何机械和化学功效的损失。

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