二铅（II）三汞（II）四氧化铬（VI），Pb2(Hg3O4)(CrO4)
Dilead(II) trimercury(II) tetraoxide chromate(VI), Pb2(Hg3O4)(CrO4).
作者信息
Klein Wilhelm, Curda Jan, Jansen Martin
机构信息
Max-Planck-Institut für Festkörperforschung, Heisenbergstrasse 1, 70569 Stuttgart, Germany.
出版信息
Acta Crystallogr C. 2005 Jun;61(Pt 6):i63-4. doi: 10.1107/S0108270105012552. Epub 2005 May 13.
PMID:15930653
Abstract
Pb2(Hg3O4)(CrO4) consists of [CrO4]2- tetrahedra, linear O-Hg-O dumbbells and divalent Pb atoms in [3+5]-coordination. The HgO2 dumbbells are condensed into [Hg3O4]2- units and can be regarded as a section of the HgO structure. The [Hg3O4]2- complex anions are connected by interstitial Pb2+ ions, while the [CrO4]2- tetrahedra are isolated.
摘要
Pb2(Hg3O4)(CrO4)由[CrO4]2-四面体、线性O-Hg-O哑铃结构以及处于[3 + 5]配位的二价Pb原子组成。HgO2哑铃结构缩合形成[Hg3O4]2-单元，可被视为HgO结构的一部分。[Hg3O4]2-复合阴离子通过间隙Pb2+离子相连，而[CrO4]2-四面体则是孤立的。
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