Electrospray ionization mass spectrometry of pyrimidine base-rubidium complexes.
作者信息
Frańska Magdalena
机构信息
Poznań University of Technology, Institute of Chemistry, Piotrowo 3, 60-965 Poznań, Poland.
出版信息
Eur J Mass Spectrom (Chichester). 2005;11(1):103-6. doi: 10.1255/ejms.723.
DOI:10.1255/ejms.723
PMID:15947449
Abstract
Nucleobases and alkali metal cations, under electrospray ionisation conditions, tend to form the so-called magic number clusters (unusually stable clusters in comparison with the neighbouring ones). The effect of the ion source parameters, namely cone voltage and desolvation temperature and relative concentrations of thymine and RbCl on the [T5+Rb]+ ion abundance has been studied.
摘要
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