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由自催化内部反应噪声驱动的时空模式。

Spatiotemporal patterns driven by autocatalytic internal reaction noise.

作者信息

Hochberg David, Zorzano M-P, Morán Federico

机构信息

Centro de Astrobiología [Consejo Superior de Investigaciones Científicas- Instituto Nacional de Técnica Aeroespacial (CSIC-INTA)] Carretera Ajalvir Km. 4, 28850 Torrejón de Ardoz, Madrid, Spain.

出版信息

J Chem Phys. 2005 Jun 1;122(21):214701. doi: 10.1063/1.1900092.

DOI:10.1063/1.1900092
PMID:15974756
Abstract

The influence that intrinsic local-density fluctuations can have on solutions of mean-field reaction-diffusion models is investigated numerically by means of the spatial patterns arising from two species that react and diffuse in the presence of strong internal reaction noise. The dynamics of the Gray-Scott (GS) model [P. Gray and S. K. Scott, Chem. Eng. Sci. 38, 29 (1983); and ibid.39, 1087 (1984); and J. Phys. Chem. 89, 22 (1985)] with a constant external source is first cast in terms of a continuum field theory representing the corresponding master equation. We then derive a Langevin description of the field theory and use these stochastic differential equations in our simulations. The nature of the multiplicative noise is specified exactly without recourse to assumptions and turns out to be of the same order as the reaction itself, and thus cannot be treated as a small perturbation. Many of the complex patterns obtained in the absence of noise for the GS model are completely obliterated by these strong internal fluctuations, but we find novel spatial patterns induced by this reaction noise in the regions of parameter space that otherwise correspond to homogeneous solutions when fluctuations are not included.

摘要

通过研究在强内部反应噪声存在下两种相互作用并扩散的物种所产生的空间模式,对内在局部密度涨落对平均场反应扩散模型解的影响进行了数值研究。首先,将具有恒定外部源的格雷 - 斯科特(GS)模型[P. 格雷和S. K. 斯科特,《化学工程科学》38, 29 (1983); 同上,39, 1087 (1984); 以及《物理化学杂志》89, 22 (1985)]的动力学转化为表示相应主方程的连续场论形式。然后,我们推导出场论的朗之万描述,并在模拟中使用这些随机微分方程。精确地确定了乘性噪声的性质,无需借助假设,结果表明其与反应本身具有相同的量级,因此不能被视为小扰动。在没有噪声的情况下,GS模型所获得的许多复杂模式被这些强内部涨落完全消除,但我们发现在不考虑涨落时对应均匀解的参数空间区域中,这种反应噪声会诱导出新的空间模式。

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