Asymmetric synthesis of cyclopropanes from lithiated aryloxiranes and alpha,beta-unsaturated Fischer carbene complexes.
作者信息
Capriati Vito, Florio Saverio, Luisi Renzo, Perna Filippo Maria, Barluenga José
机构信息
Dipartimento Farmaco-Chimico, Università di Bari, Via E. Orabona 4, I-70126 Bari, Italy.
出版信息
J Org Chem. 2005 Jul 22;70(15):5852-8. doi: 10.1021/jo050443r.
PMID:16018677
Abstract
A diastereo- and enantiospecific formation of tetrasubstituted cyclopropane carbene complexes and cyclopropanecarboxylates from lithiated aryloxiranes and alpha,beta-unsaturated Fischer carbene complexes is described.
摘要
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