Unambiguously distinguishing Si[3Si,1Al] and Si[3Si,1OH] stuctural units in zeolite by 1H/29Si/27Al triple resonance solid state NMR spectroscopy.

作者信息

Luo Qing, Yang Jun, Hu Wei, Zhang Mingjin, Yue Yong, Ye Chaohui, Deng Feng

机构信息

Wuhan Institute of Physics and Mathematics, State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, The Chinese Academy of Sciences, Wuhan City, Hubei Province 430071, PR China.

出版信息

Solid State Nucl Magn Reson. 2005 Jul;28(1):9-12. doi: 10.1016/j.ssnmr.2005.02.004.

DOI:10.1016/j.ssnmr.2005.02.004

PMID:16026686

Abstract

We present an experimentally feasible triple-resonance NMR method that establishes the correlation among three different nuclei, avoiding the difficulty to directly explore the weak coupling between two NMR nuclei, such as (29)Si and (27)Al. Using this method, we are able to give an unambiguous assignment to the various peaks in (29)Si CP NMR spectrum of MCM-22 zeolite and discriminate (29)Si signals from SiOHAl and SiOH groups. In addition, in combination with (1)H/(27)Al double-resonance technique, the (1)H/(27)Al/(29)Si triple-resonance experiment suggests the presence of two different kinds of Brönsted acid sites in H-MCM-22 zeolite.

摘要