Wang Ge, Si Lichun, Yang Huai, Cai Fuli, Wang Zhiqiang, Duan Xue
School of Material Science and Engineering, University of Science and Technology Beijing, Beijing 100083, P.R. China.
J Nanosci Nanotechnol. 2005 Jun;5(6):917-22. doi: 10.1166/jnn.2005.138.
A simple chemical method to obtain nanopolymers with special morphology is reported. The key to the success of this preparation was the use of layered double hydroxides (LDHs), a two-dimensional host material, as template. Typical procedures include in-situ polymerization of the monomers in the interlayers of the LDH template, followed by the dissolution of LDH sheets so that the formed polymers can be free and collected. The obtained results demonstrate potential of LDHs as tools for the controlled synthesis of nanopolymers with platelike morphology.
报道了一种获得具有特殊形态的纳米聚合物的简单化学方法。该制备成功的关键在于使用层状双氢氧化物(LDHs),一种二维主体材料,作为模板。典型步骤包括在LDH模板的层间原位聚合单体,随后溶解LDH片层,以便形成的聚合物能够游离并收集。所得结果证明了LDHs作为可控合成具有片状形态纳米聚合物工具的潜力。