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基于锌卟啉的三维配位网络中的可逆单晶到单晶客体交换

Reversible single-crystal-to-single-crystal guest exchange in a 3-D coordination network based on a zinc porphyrin.

作者信息

Deiters Emmanuel, Bulach Véronique, Hosseini Mir Wais

机构信息

Laboratoire de Chimie de Coordination Organique, UMR CNRS 7140, Université Louis Pasteur, F-67000, Strasbourg, France.

出版信息

Chem Commun (Camb). 2005 Aug 21(31):3906-8. doi: 10.1039/b508135c. Epub 2005 Jul 8.

DOI:10.1039/b508135c
PMID:16075067
Abstract

A self-complementary tecton based on a zinc porphyrin core bearing two pyridines at the opposite meso positions leads to the formation of a 3-D coordination network in the crystalline phase which offers channels which are filled with solvent molecules; reversible exchange of the guest molecules has been proven to take place in a single-crystal-to-single-crystal type transformation demonstrating the robustness of the coordination framework.

摘要

一种基于锌卟啉核心的自互补构造体，在相对的中位位置带有两个吡啶，在结晶相中形成三维配位网络，该网络提供充满溶剂分子的通道；客体分子的可逆交换已被证明在单晶到单晶类型的转变中发生，这证明了配位框架的稳健性。

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