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Di-mu-chloro-1:2kappa2Cl;3:4kappa2Cl-hexachloro-1kappa3Cl,4kappa3Cl-tetra-mu-dimethylglycine-2:3kappa8O:O'-tetracopper(II).

作者信息

Ramos Silva M, Matos Beja A, Paixão J A, Martin-Gil J

机构信息

CEMDRX, Departamento de Física, Faculdade de Ciências e Tecnologia, Universidade de Coimbra, P-3004-516 Coimbra, Portugal.

出版信息

Acta Crystallogr C. 2005 Aug;61(Pt 8):m380-2. doi: 10.1107/S0108270105021591. Epub 2005 Jul 23.

DOI:10.1107/S0108270105021591
PMID:16082086
Abstract

The title compound, [Cu(NO3)2(C6H10N4)2], crystallizes in the centrosymmetric space group P21/c with a unit cell containing two tetranuclear copper(II) complexes sited on crystallographic inversion centres. The coordination geometry around the central Cu atoms is square pyramidal, with four O atoms in the basal plane and a Cl atom in the apical position. The lateral CuCl4 groups are flattened tetrahedral. The bridging dimethylglycine molecules are present in the dipolar zwitterionic form. The tetranuclear copper complexes exist as isolated entities since only intramolecular hydrogen bonds are found.

摘要

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