Ho Lionel, Newcombe Gayle
Australian Water Quality Centre, a partner in the Cooperative Research Centre for Water Quality and Treatment, PMB 3, Salisbury, SA 5108, Australia.
Water Res. 2005 Sep;39(15):3668-74. doi: 10.1016/j.watres.2005.06.028.
The effect of natural organic material (NOM) and turbidity on the powdered activated carbon (PAC) adsorption of the odour compound 2-methylisoborneol (MIB) was evaluated during alum coagulation. The character of the flocs, in terms of their size and fractal dimensions (Df), was used to interpret the observed adsorption behaviour of MIB during the coagulation process. As the alum dose was increased, the adsorption of MIB decreased. This was determined to be due to the size of the flocs, with larger flocs incorporating PAC into their structure, reducing the efficiency of mixing, and the bulk diffusion kinetics for the MIB molecule. The presence of turbidity also reduced MIB adsorption due to the formation of larger flocs. The character of NOM was found to have a greater influence on the adsorption of MIB than the floc structure.
在明矾混凝过程中,评估了天然有机物质(NOM)和浊度对粉末活性炭(PAC)吸附气味化合物2-甲基异冰片(MIB)的影响。根据絮体的大小和分形维数(Df)来解释在混凝过程中观察到的MIB吸附行为。随着明矾剂量的增加,MIB的吸附量减少。这被确定是由于絮体的大小,较大的絮体将PAC纳入其结构中,降低了混合效率以及MIB分子的体相扩散动力学。浊度的存在也由于形成较大的絮体而降低了MIB的吸附。发现NOM的特性对MIB吸附的影响大于絮体结构。