Illescas Beatriz M, Martín Nazario, Poater Jordi, Solà Miquel, Aguado Gemma P, Ortuño Rosa M
Departamento de Química Orgánica, Facultad de Química, Universidad Complutense, E-28040 Madrid, Spain.
J Org Chem. 2005 Aug 19;70(17):6929-32. doi: 10.1021/jo0509197.
The first diastereoselective synthesis of fulleropyrrolidines endowed with diastereomerically pure functionalized cyclobutanes is reported. The new C(60)-based cyclobutane derivatives 7a,b and 9 are suitably functionalized for further incorporation into peptide surrogates.
报道了具有非对映体纯官能化环丁烷的富勒吡咯烷的首次非对映选择性合成。新型的基于C(60)的环丁烷衍生物7a、b和9经过适当官能化，可进一步用于合成肽模拟物。
