Brik M G, Avram N M, Avram C N
Fukui Institute for Fundamental Chemistry, Kyoto University, 34-4 Takano, Kyoto 606-8103, Japan.
Spectrochim Acta A Mol Biomol Spectrosc. 2006 Mar 1;63(3):759-65. doi: 10.1016/j.saa.2005.06.027. Epub 2005 Aug 10.
A detailed analysis of the energy level structure of tetrahedrally coordinated V(3+) ion in lithium aluminum oxide LiAlO(2) (gamma-phase) and lithium dioxogallate LiGaO(2) is performed using the exchange charge model of the crystal field theory. The parameters of the crystal field acting on the V(3+) optical electrons are calculated from crystal structure data assuming C(1) point symmetry of the VO(4) impurity center in LiAlO(2) and LiGaO(2). Crystal field splitting of all five LS terms of the V(3+) ion ((3)F, (3)P, (1)S, (1)D, (1)G) is calculated. The energy levels obtained are compared with experimental absorption spectra and results of application of other crystal field models (the angular overlap model and Racah theory) to the considered crystals; though only one fitting parameter of the exchange charge model was used, a good agreement with experimental data on the ground and excited state absorption is demonstrated.
