一氧化氮从可再生的、溶胶-凝胶封装的钌-双水杨醛缩乙二胺-亚硝酰配合物中的光化学释放。
Photochemical release of nitric oxide from a regenerable, sol-gel encapsulated Ru-salen-nitrosyl complex.
作者信息
Bordini Jeane, Ford Peter C, Tfouni Elia
机构信息
Departamento de Química - Faculdade de Filosofia, Ciências e Letras de Ribeirão Preto, Universidade de São Paulo, Av. Bandeirantes 3900, 14040-901 São Paulo, Brazil.
出版信息
Chem Commun (Camb). 2005 Sep 7(33):4169-71. doi: 10.1039/b507407j. Epub 2005 Jul 25.
Light activation leads to release of NO from a silicate sol-gel material SG-RuNO prepared from the ruthenium complex, [Ru(salen)(OH2)(NO)]+ (salen = N,N'-bis-(salicylidene)ethyl-enediaminato); after photochemical NO photolabilization, SG-RuNO can be regenerated from the spent material via the subsequent reaction with aqueous nitrite.
光激活会导致从由钌配合物[Ru(salen)(OH2)(NO)]+（salen = N,N'-双（水杨醛亚胺基）乙二胺）制备的硅溶胶-凝胶材料SG-RuNO中释放出一氧化氮；在光化学作用下一氧化氮发生光解后，用过的材料可通过随后与亚硝酸盐水溶液反应而使SG-RuNO再生。
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