功能性二茂钛的模块化高效合成。
A modular and efficient synthesis of functional titanocenes.
作者信息
Gansäuer Andreas, Franke Dieter, Lauterbach Thorsten, Nieger Martin
机构信息
Kekulé-Institut für Organische Chemie und Biochemie und Institut für Anorganische Chemie der Universität Bonn, Gerhard Domagk Strasse 1, 53121 Bonn, Germany.
出版信息
J Am Chem Soc. 2005 Aug 24;127(33):11622-3. doi: 10.1021/ja054185r.
A modular synthesis of functional titanocenes featuring building blocks is described. The approach allows straightforward access to large numbers of structurally diverse titanocenes that are pertinent for catalysis, structural studies, and bioinorganic chemistry. Among the functional groups introduced are amino acids, sugars, and fluorescence labels that are attached to the cyclopentadienyl ligand as esters and amides.
本文描述了一种以构建模块为特色的功能性钛茂的模块化合成方法。该方法能够直接合成大量结构多样的钛茂，这些钛茂在催化、结构研究和生物无机化学领域具有重要意义。所引入的官能团包括氨基酸、糖类和荧光标记物，它们以酯和酰胺的形式连接到环戊二烯基配体上。
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