Wouterse A, Plapp M, Philipse A P
Van't Hoff Laboratory for Physical and Colloid Chemistry, Debye Institute, Utrecht University, Padualaan 8, 3584 CH, Utrecht, The Netherlands.
J Chem Phys. 2005 Aug 1;123(5):054507. doi: 10.1063/1.1991852.
Local structural arrest in random packings of colloidal or granular spheres is quantified by a caging number, defined as the average minimum number of randomly placed spheres on a single sphere that immobilize all its translations. We present an analytic solution for the caging number for two-dimensional hard disks immobilized by neighbor disks which are placed at random positions under the constraint of a nonoverlap condition. Immobilization of a disk with radius r = 1 by arbitrary larger neighbor disks with radius r > or = 1 is solved analytically, whereas for contacting neighbors with radius 0 < r < 1, the caging number can be evaluated accurately with an approximate excluded volume model that also applies to spheres in higher Euclidean dimension. Comparison of our exact two-dimensional caging number with studies on random disk packing indicates that it relates to the average coordination number of random loose packing, whereas the parking number is more indicative for coordination in random dense packing of disks.
通过一个笼数来量化胶体或颗粒球体随机堆积中的局部结构停滞,笼数定义为单个球体上随机放置的、使该球体所有平移都固定的球体的平均最小数量。我们给出了二维硬磁盘笼数的解析解,这些硬磁盘由放置在非重叠条件约束下随机位置的相邻磁盘固定。半径(r = 1)的磁盘被任意半径(r \geq 1)的较大相邻磁盘固定的情况可通过解析方法求解,而对于半径(0 < r < 1)的接触相邻磁盘,笼数可以用一个近似排除体积模型精确评估,该模型也适用于更高欧几里得维度的球体。将我们精确的二维笼数与随机磁盘堆积的研究进行比较表明,它与随机松散堆积的平均配位数相关,而停放数更能指示磁盘随机密集堆积中的配位情况。