Devic Thomas, Serre Christian, Audebrand Nathalie, Marrot Jérôme, Férey Gérard
Institut Lavoisier, UMR CNRS 8637, Université de Versailles Saint-Quentin-en-Yvelines, 45 avenue des Etats-Unis, 78035 Versailles Cedex, France.
J Am Chem Soc. 2005 Sep 21;127(37):12788-9. doi: 10.1021/ja053992n.
A lanthanide-based metal organic framework, formulated Tb(C27H15O6)(H2O).2C6H11OH, has been solvothermally synthesized using the extended rigid tritopic ligand 1,3,5-tribenzoate. Included free solvent could be removed upon heating, and the resulting material presents large 1-D micropores (free diameter = 10 A) and a high surface area (SLangmuir > 1000 m2.g-1).
一种基于镧系元素的金属有机骨架化合物，化学式为Tb(C27H15O6)(H2O).2C6H11OH，已通过溶剂热法使用扩展刚性三齿配体1,3,5-三苯甲酸酯合成。加热时可除去其中所含的游离溶剂，所得材料呈现出大的一维微孔（自由直径 = 10 Å）和高比表面积（Langmuir比表面积> 1000 m2·g-1）。
