无过渡金属和有机溶剂：一种在水中将醇选择性氧化为醛和酮的高效厌氧过程。
Transition-metal- and organic-solvent-free: a highly efficient anaerobic process for selective oxidation of alcohols to aldehydes and ketones in water.
作者信息
Gogoi Pranjal, Konwar Dilip
机构信息
Organic Chemistry Division, Regional Research Laboratory, Jorhat, 785006, Assam, India.
出版信息
Org Biomol Chem. 2005 Oct 7;3(19):3473-5. doi: 10.1039/b509527a. Epub 2005 Sep 1.
DOI:10.1039/b509527a
PMID:16172681
Abstract
A new system, I2-KI-K2CO3-H2O, selectively oxidized alcohols to aldehydes and ketones under anaerobic condition in water at 90 degrees C with excellent yields. The process is green, mild and inexpensive.
摘要
一种新体系I₂-KI-K₂CO₃-H₂O，在90℃的水中厌氧条件下能将醇选择性氧化为醛和酮，产率优异。该过程绿色、温和且成本低廉。
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