Velusamy Subbarayan, Ahamed Muneer, Punniyamurthy T
Department of Chemistry, Indian Institute of Technology Guwahati, Guwahati 781039, India.
Org Lett. 2004 Dec 23;6(26):4821-4. doi: 10.1021/ol048195t.
[reaction: see text] Oxidation of alcohols to aldehydes and ketones has been studied in high yields using molecular oxygen and a catalytic amount of 1 in toluene under stirring (ca. 100 degrees C). The reactions of primary alcohols are faster compared to secondary alcohols and the catalyst 1 can be recycled without loss of activity.
[反应:见正文] 在搅拌(约100℃)下,使用分子氧和催化量的1在甲苯中研究了醇氧化为醛和酮的反应,产率很高。与仲醇相比,伯醇的反应更快,并且催化剂1可以循环使用而不损失活性。