同结构的二价钼卟啉和N-杂卟啉配合物的合成。
The synthesis of isostructural Mo2+ porphyrin and N-confused porphyrin complexes.
作者信息
Harvey John D, Shaw Janet L, Herrick Richard S, Ziegler Christopher J
机构信息
Department of Chemistry, University of Akron, Akron, OH 44325-3601, USA.
出版信息
Chem Commun (Camb). 2005 Oct 7(37):4663-5. doi: 10.1039/b508913a. Epub 2005 Aug 23.
DOI:10.1039/b508913a
PMID:16175285
Abstract
We have synthesized the first early transition metal N-confused porphyrin complex Mo(NCTPP)(pip)2; this species is isostructural to its normal porphyrin analog Mo(TPP)(pip)2 but exhibits significant electronic differences arising from the inversion of a single pyrrolic group.
摘要
我们合成了首个早期过渡金属氮杂卟啉配合物Mo(NCTPP)(pip)₂；该物种与其正常卟啉类似物Mo(TPP)(pip)₂同构，但由于单个吡咯基团的反转而表现出显著的电子差异。
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