由乙酸锰（III）介导的稠合三环γ-内酯的合成。
Synthesis of fused tricyclic gamma-lactones mediated by manganese(III) acetate.
作者信息
Hulcoop David G, Burton Jonathan W
机构信息
Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, UK CB2 1EW.
出版信息
Chem Commun (Camb). 2005 Oct 7(37):4687-9. doi: 10.1039/b508529b. Epub 2005 Aug 24.
DOI:10.1039/b508529b
PMID:16175293
Abstract
Exposure of cyclic alkenes bearing a carboxylic acid and a malonate group to manganese(III) acetate and an appropriate copper(II) salt provides the corresponding tricyclic gamma-lactones in good yield.
摘要
使带有羧酸和丙二酸酯基团的环状烯烃与乙酸锰(III)和适当的铜(II)盐反应，可高产率地得到相应的三环γ-内酯。
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