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中试规模的两阶段工艺:产酸发酵制氢与产甲烷过程的结合。

Pilot-scale two-stage process: a combination of acidogenic hydrogenesis and methanogenesis.

作者信息

Han S K, Kim S H, Kim H W, Shin H S

机构信息

Department of Environmental Health, Korea National Open University, 169 Dongsung-dong, Jongno-gu, Seoul 110-791, Korea.

出版信息

Water Sci Technol. 2005;52(1-2):131-8.

Abstract

This study was performed to optimize both acidogenic hydrogenesis and methanogenesis, and then to develop a pilot-scale two-stage process producing not only CH4 but also H2. Firstly, acidogenic hydrogenesis of food waste was examined in pilot-scale leaching-bed reactors using dilution rate (D) as a tool to improve the environmental conditions. The maximum efficiency of 71.4% was obtained by adjusting D from 4.5 to 2.5 d(-1) depending on the state of degradation. Secondly, the wastewater from acidogenic hydrogenesis was converted to CH4 in a pilot-scale UASB reactor. The COD removal efficiency exceeded 95% up to the loading rates of 13.1 g COD/Ld, which corresponded to HRT of 0.25 d (6 h). Lastly, a pilot-scale two-stage process was devised based on a combination of acidogenic hydrogenesis and methanogenesis. Over 120 days, the pilot-scale process resulted in large VS reduction of 70.9% at the high loading rate of 12.5 kg VS/m3/d in a short SRT of 8 days.

摘要

本研究旨在优化产酸制氢和产甲烷过程,进而开发一种中试规模的两段式工艺,该工艺不仅能产生CH4,还能产生H2。首先,在中试规模的浸出床反应器中,以稀释率(D)作为改善环境条件的工具,研究了食物垃圾的产酸制氢过程。根据降解状态将D从4.5调整至2.5 d(-1),获得了71.4%的最大效率。其次,在中试规模的UASB反应器中,将产酸制氢产生的废水转化为CH4。在高达13.1 g COD/Ld的负荷率下,COD去除效率超过95%,这对应于0.25 d(6小时)的水力停留时间(HRT)。最后,基于产酸制氢和产甲烷的组合设计了一种中试规模的两段式工艺。在120多天的时间里,该中试规模工艺在8天的短污泥停留时间(SRT)和12.5 kg VS/m3/d的高负荷率下,实现了70.9%的大量挥发性固体(VS)减少。

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