Hartley Ken, Lant Paul
Ken Hartley Pty Ltd, Queensland, Australia.
Biotechnol Bioeng. 2006 Oct 20;95(3):384-98. doi: 10.1002/bit.20929.
The aim of this work was to demonstrate at pilot scale a high level of energy recovery from sewage utilising a primary Anaerobic Migrating Bed Reactor (AMBR) operating at ambient temperature to convert COD to methane. The focus is the reduction in non-renewable CO(2) emissions resulting from reduced energy requirements for sewage treatment. A pilot AMBR was operated on screened sewage over the period June 2003 to September 2004. The study was divided into two experimental phases. In Phase 1 the process operated at a feed rate of 10 L/h (HRT 50 h), SRT 63 days, average temperature 28 degrees C and mixing time fraction 0.05. In Phase 2 the operating parameters were 20 L/h, 26 days, 16 degrees C and 0.025. Methane production was 66% of total sewage COD in Phase 1 and 23% in Phase 2. Gas mixing of the reactor provided micro-aeration which suppressed sulphide production. Intermittent gas mixing at a useful power input of 6 W/m(3) provided satisfactory process performance in both phases. Energy consumption for mixing was about 1.5% of the energy conversion to methane in both operating phases. Comparative analysis with previously published data confirmed that methane supersaturation resulted in significant losses of methane in the effluent of anaerobic treatment systems. No cases have been reported where methane was considered to be supersaturated in the effluent. We have shown that methane supersaturation is likely to be significant and that methane losses in the effluent are likely to have been greater than previously predicted. Dissolved methane concentrations were measured at up to 2.2 times the saturation concentration relative to the mixing gas composition. However, this study has also demonstrated that despite methane supersaturation occurring, micro-aeration can result in significantly lower losses of methane in the effluent (<11% in this study), and has demonstrated that anaerobic sewage treatment can genuinely provide energy recovery. The goal of demonstrating a high level of energy recovery in an ambient anaerobic bioreactor was achieved. An AMBR operating at ambient temperature can achieve up to 70% conversion of sewage COD to methane, depending on SRT and temperature.
这项工作的目的是在中试规模上证明,利用在环境温度下运行的一级厌氧移动床反应器(AMBR)从污水中实现高水平的能量回收,将化学需氧量(COD)转化为甲烷。重点是减少因污水处理能源需求降低而产生的不可再生二氧化碳排放量。一个中试AMBR在2003年6月至2004年9月期间对经过筛选的污水进行处理。该研究分为两个实验阶段。在第一阶段,该工艺以10升/小时的进料速率(水力停留时间50小时)、污泥停留时间63天、平均温度28摄氏度和混合时间分数0.05运行。在第二阶段,运行参数为20升/小时、26天、16摄氏度和0.025。第一阶段甲烷产量占污水总COD的66%,第二阶段为23%。反应器的气体混合提供了微曝气,抑制了硫化物的产生。在6瓦/立方米的有效功率输入下进行间歇气体混合,在两个阶段都提供了令人满意的工艺性能。两个运行阶段的混合能耗约为甲烷能量转化的1.5%。与先前发表的数据进行比较分析证实,甲烷过饱和导致厌氧处理系统的出水甲烷大量损失。尚未有报道称出水甲烷被认为过饱和的情况。我们已经表明,甲烷过饱和可能很显著,并且出水中的甲烷损失可能比先前预测的更大。相对于混合气体组成,测得的溶解甲烷浓度高达饱和浓度的2.2倍。然而,这项研究还表明,尽管发生了甲烷过饱和,但微曝气可使出水中的甲烷损失显著降低(本研究中<11%),并证明了厌氧污水处理能够真正实现能量回收。在环境温度下的厌氧生物反应器中实现高水平能量回收的目标得以实现。根据污泥停留时间和温度,在环境温度下运行的AMBR可实现高达70%的污水COD转化为甲烷。