柔性自组装卟啉超分子
Flexible self-assembling porphyrin supramolecules.
作者信息
Johnstone Ken D, Yamaguchi Kentaro, Gunter Maxwell J
机构信息
School of Biological, Biomedical and Molecular Sciences, University of New England, Armidale, NSW 2350, Australia.
出版信息
Org Biomol Chem. 2005 Aug 21;3(16):3008-17. doi: 10.1039/b506987d. Epub 2005 Jul 4.
The design and chemical synthesis of a series of hybrid flexible self-assembling supramolecules utilising both crown ether-naphthalene diimide host-guest chemistry and metalloporphyrin-pyridyl coordination is discussed. The resulting compound structures and dynamics are probed using a variety of techniques, including diffusion ordered NMR spectroscopy (DOSY) and cold-spray ionisation mass spectrometry (CSI-MS).
本文讨论了一系列利用冠醚-萘二酰亚胺主客体化学和金属卟啉-吡啶配位的混合柔性自组装超分子的设计与化学合成。使用多种技术对所得化合物的结构和动力学进行了探测，包括扩散有序核磁共振光谱（DOSY）和冷喷雾电离质谱（CSI-MS）。
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