四聚[低聚（对亚苯基乙烯撑）]卟啉与C60在水中聚集体中的连续能量与电子转移
Sequential energy and electron transfer in aggregates of tetrakis[oligo(p-phenylene vinylene)] porphyrins and C60 in water.
作者信息
Wolffs Martin, Hoeben Freek J M, Beckers Edwin H A, Schenning Albertus P H J, Meijer E W
机构信息
Laboratory of Macromolecular and Organic Chemistry, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands.
出版信息
J Am Chem Soc. 2005 Oct 5;127(39):13484-5. doi: 10.1021/ja054406t.
Chiral aggregation of oligo(p-phenylene vinylene)-functionalized Zn and free-base porphyrins is observed in water. The formation of mixed assemblies containing both porphyrins results in sequential energy transfer from OPV via zinc porphyrin to free-base porphyrin. Furthermore, the incorporation of C60 as electron acceptor yields a charge separated state by ultimate electron transfer.
在水中观察到了寡聚（对亚苯基乙烯基）功能化的锌卟啉和自由碱卟啉的手性聚集。含有两种卟啉的混合组装体的形成导致了能量从寡聚（对亚苯基乙烯基）经由锌卟啉依次转移到自由碱卟啉。此外，引入C60作为电子受体通过最终的电子转移产生了电荷分离态。
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