Porcar L, Warr G G, Hamilton W A, Butler P D
National Institute of Standards and Technology, Center for Neutron Research, Gaithersburg, Maryland 20899, USA.
Phys Rev Lett. 2005 Aug 12;95(7):078302. doi: 10.1103/PhysRevLett.95.078302. Epub 2005 Aug 11.
An entropically stabilized cetylpyridinium chloride, hexanol, and heavy brine lyotropic lamellar phase subjected to shear flow has been observed here by small angle neutron scattering to undergo collapse of smectic order above a threshold shear rate. The results are compared with theories predicting that such a lamellar phase sheared above a critical rate should lose its stability by a loss of resistance to compression due to the suppression of membrane fluctuations.
通过小角中子散射观察到,一种由氯化十六烷基吡啶、己醇和重卤水形成的熵稳定溶致层状相在剪切流作用下,当剪切速率超过阈值时,近晶有序会发生崩塌。将这些结果与理论预测进行了比较,该理论认为,这种层状相在超过临界速率剪切时,由于膜波动受到抑制,对压缩的抵抗力丧失,从而失去稳定性。