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水热法合成YLiF4:Er、Tm、Yb的上转换发光特性

[Upconversion luminescence properties of YLiF4:Er, Tm, Yb synthesized by hydrothermal method].

作者信息

Pei Xiao-jiang, Hou Yan-bing, Xu Zheng, Zhao Su-ling, Teng Feng

机构信息

Institute of Optoelectronic Technology, Beijing Jiaotong University, Key Laboratory of Information Storage and Display, Beijing 100044, China.

出版信息

Guang Pu Xue Yu Guang Pu Fen Xi. 2005 Jun;25(6):819-23.

Abstract

YLiF4 codoped with Er3+, Tm3+ and Yb3+ ions was synthesized by hydrothermal method. The absorption spectra and upconversion spectra excited at 980 nm were investigated. Under the excitation of infrared photons, strong white emission can be obtained. According to the value of n obtained from the power law, the 484 nm blue emission, 524 and 552 nm green emission, and 665 nm red emission are all due to two photon process, while the UV emission is attributed to three photon process. The authors also analyzed the upconversion mechanism and process.

摘要

采用水热法合成了共掺杂Er3+、Tm3+和Yb3+离子的YLiF4。研究了在980nm激发下的吸收光谱和上转换光谱。在红外光子激发下,可以获得强烈的白色发射。根据幂律得到的n值,484nm的蓝色发射、524和552nm的绿色发射以及665nm的红色发射均归因于双光子过程,而紫外发射则归因于三光子过程。作者还分析了上转换机制和过程。

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