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[掺Er3+、Yb3+和Tm3+氟化物玻璃的红色上转换发光研究]

[Study on red up-conversion luminescence of fluoride glasses doped with Er3+, Yb3+ and Tm3+].

作者信息

Yan Lei, Liu Zheng-wei, Yang Xiao-liang

机构信息

Department of Modern Physics, Xiangtan University, Xiangtan 411105, China.

出版信息

Guang Pu Xue Yu Guang Pu Fen Xi. 2005 Jun;25(6):824-7.

Abstract

When the quality of Er2O3 is 10 times the former, the authors found that its character of up-conversion luminescence is distinct. Then the authors studied the luminescence system of Es3+ /Tm3+, Er3+ /Er3+ and Er3+ /Yb3+ /Tm3+ and their character of upconversion and fluorescence spectrum at 980 nm. In addition, the authors studied the relation between the three systems and the consistency of Er2O3. The authors found that the intensity of green and red light changed with the consistence of Er3+ in the experiment. It's the consistence of Er3+ that is the most causative. The chance is equal for each lanthanonion that makes up the luminescence system in the uniformity matter. With the distance between each pair of lanthanonions in the luminescence system is changed, the luminescence system and the color of the up-conversion luminescence also changed.

摘要

当三氧化二铒的质量为之前的10倍时,作者发现其向上转换发光特性明显。然后作者研究了铒3+ /铥3+、铒3+ /铒3+以及铒3+ /镱3+ /铥3+的发光体系及其向上转换特性和980纳米处的荧光光谱。此外,作者研究了这三个体系之间的关系以及三氧化二铒的一致性。作者发现在实验中绿光和红光的强度随铒3+的一致性而变化。铒3+的一致性是最具决定性的因素。在均匀性问题上,构成发光体系的每个镧系离子的机会是均等的。随着发光体系中每对镧系离子之间距离发生变化,发光体系和向上转换发光的颜色也发生了变化。

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