三氟甲磺酸银（I）催化的醇和羧酸对惰性烯烃的分子内加成反应。
Intramolecular additions of alcohols and carboxylic acids to inert olefins catalyzed by silver(I) triflate.
作者信息
Yang Cai-Guang, Reich Nicholas W, Shi Zhangjie, He Chuan
机构信息
Department of Chemistry, University of Chicago, 5735 South Ellis Avenue, Chicago, Illinois 60637, USA.
出版信息
Org Lett. 2005 Oct 13;7(21):4553-6. doi: 10.1021/ol051065f.
PMID:16209477
Abstract
[reactions: see text] Intramolecular additions of hydroxyl or carboxyl groups to inert olefins catalyzed by simple silver(I) triflate are described. Good to excellent yields can be obtained for a range of substrates under relatively mild conditions. This reaction represents one of the simplest methods to construct cyclic ethers or lactones.
摘要
[反应：见正文] 描述了由简单的三氟甲磺酸银（I）催化的羟基或羧基对惰性烯烃的分子内加成反应。在相对温和的条件下，一系列底物都能获得良好至优异的产率。该反应是构建环醚或内酯的最简单方法之一。
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