Perrin Christian L, Tardy Philippe M J, Sorbie Ken S, Crawshaw John C
Schlumberger Cambridge Research, High Cross, Madingley Road, Cambridge CB3 0EL, UK.
J Colloid Interface Sci. 2006 Mar 15;295(2):542-50. doi: 10.1016/j.jcis.2005.09.012. Epub 2005 Oct 10.
The in situ rheology of polymeric solutions has been studied experimentally in etched silicon micromodels which are idealizations of porous media. The rectangular channels in these etched networks have dimensions typical of pore sizes in sandstone rocks. Pressure drop/flow rate relations have been measured for water and non-Newtonian hydrolyzed-polyacrylamide (HPAM) solutions in both individual straight rectangular capillaries and in networks of such capillaries. Results from these experiments have been analyzed using pore-scale network modeling incorporating the non-Newtonian fluid mechanics of a Carreau fluid. Quantitative agreement is seen between the experiments and the network calculations in the Newtonian and shear-thinning flow regions demonstrating that the 'shift factor,'alpha, can be calculated a priori. Shear-thickening behavior was observed at higher flow rates in the micromodel experiments as a result of elastic effects becoming important and this remains to be incorporated in the network model.
聚合物溶液的原位流变学已在蚀刻硅微模型中进行了实验研究,这些微模型是多孔介质的理想化模型。这些蚀刻网络中的矩形通道具有砂岩岩石中典型的孔径尺寸。已测量了水和非牛顿水解聚丙烯酰胺(HPAM)溶液在单个直矩形毛细管以及此类毛细管网络中的压降/流速关系。这些实验结果已使用结合了卡雷奥流体非牛顿流体力学的孔隙尺度网络模型进行了分析。在牛顿流和剪切变稀流动区域,实验与网络计算之间呈现出定量一致性,表明“位移因子”α可以预先计算得出。由于弹性效应变得重要,在微模型实验中较高流速下观察到了剪切增稠行为,而这仍有待纳入网络模型。